The Hydrogen atom

© 2003 David Barwacz

2/03/2004

 

daveb@triton.net

http://members.triton.net/daveb

 

 

 

Abstract

 

In this paper I will use the previously developed geometry and scalar energy equation to develop an equation for the energy levels of hydrogenic atoms. The equation developed is identical in form to the energy equation developed by Dirac. 

 

The general form of the energy equation

 

We start with the scalar energy formula developed previously, (Vector and Scalar Energy © 2003 David Barwacz).

 

 

    where  .

 

Since  and    we can write the energy equation as

 

 

 

The first term is the measurable energy and is all we are concerned with.

 

In Figure 15 below, all vectors are depicted as momentum and the  vectors have been added.  is just the vector representation of

 

 

 

 

 

In the following discussion, I will simply not use the arrow when referring to the magnitude of a vector. From figure 15 we can write the following equations:

 

    eq  6.4

 

                               eq. 6.5

 

                        eq 6.6

 

Let                       eq 6.61

 

In general,  can be any real number.

 

Next we define two numbers  and as follows:

 

    and            eq. 6.7

 

Combining 6.7 with 6.6, 6.61 and 6.5 and substituting into 6.4 yields:

 

 

 

 

Multiplying each term by  and simplifying yields:

 

 

 

 

Dividing every term by  and rearranging yields:

 

 

 

Multiplying by c and taking the square root results in

 

                 eq.  6.10

 

 

The above formula is the exact form of the Dirac energy equation for hydrogen.

This equation is a general energy equation for any relativistic system and is not limited to quantum mechanics.

 

Placing the following specific restrictions on the values of ,  and  reduces this to Diracs solution for hydrogen.

 

and  are limited to positive integer  values and .

 

 

Some insight into just what these quantum conditions mean can be gained by representing the quantum equation graphically as shown below:

 

 

 

From the above diagram it can be seen that  and  must be equal and that

 

The quantum conditions can be written in terms of the angles as:

 

  and

 

 

 

Summary

 

It is very interesting that this equation can be arrived at with absolutely no assumptions of fields. Dirac added a scalar and vector field to his differential equations to arrive at an equation of this form. It may be possible that, just as Dirac found intrinsic spin to be a consequence of his matrices, fields may be a consequence of this space/time geometry.